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Belfastboy,
First, if you haven't, please read the Step-By-Step Naphtha Bath thread.
Buler is right, very few hats will require the type of cleaning you get with a naphtha bath. Try vacuuming, steaming, and brushing first. Steam and a brush will work wonders on a felt hat. As for the liner, I usually live with a little discoloration. It is, after all, an old hat that has been worn. Should you attempt to destitch and remove it, you'll never get it stitched back in unless by an experienced professional. I don't think your average seamstress can pull this off, but I may be wrong.
If you choose to go the naphtha route, leave the hat in one piece. Treat the leather sweat well with Lexol or another leather conditioner both before and after. Read the step-by-step thread, and maybe this thread started by me.
Thanks, I could not find that thread but will attempt the steaming brush first and see what comes out and only as a last resort attempt the naptha.