I second @jlee562 and suggest you look at the polypropylene hats offered by Akubra. My Akubra Country Club gets a lot of use in the summer and it still looks great.
I know this is a dead thread, but it is still popping up for those searching for waterproofing for straws, so I’ll say this: I’ve had bad experiences with paper straws when they get wet, and when the coating wears off they fully sag and get very delicate when touched with water. However, there are straws that are waterproof and hold up well to water.
Kevin from “Hats and Guitars” is a hat seller and maker for a long time and goes into different straws and their properties. Just for instance, Mexican Palm Straw (woven from the Mexican Fan Palm tree, Washingtonia robusta, or the “Skyduster”) is so waterproof that it is designed to be able to wear in the rain and used by American, Mexican, and South American cowboys for their work. It can be dipped in water and worn to provide cooling, and can be shaped by getting it soaking wet and tying it into a desired position.
Similarly, Hemp hats aren’t damaged by rain and are very tough. Sea grass is also known for being able to take moisture well.
If you want to wear a natural hat that will protect you from rain and sun, it is very possible and you don’t need to go to synthetics to accomplish this.
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