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Soaking the hat whole in naphtha can indeed clean it up a bit. I know of only one person who has had naphtha do any perceptible damage to his hat. It was our very own Rick Blaine, quite some time ago. The sweatband on his hat was quite damaged by it and the dye (or something) in the leather transfered to the felt.
FWIW (keeping in mind that I'm no chemist), I've used both VM&P (varnish maker's and painter's) naphtha (from the paint department at hardware store) and Coleman brand camp fuel. They sure don't look or smell like they're the same thing.
Donning a pair of rubber gloves and scrubbing the naphtha (or whatever solvent you're using) into the felt might get out some soiling that the soaking alone will leave in. But if you're not taking the hat apart, well, getting at some of that soiling might be difficult, if not impossible.
I'm a bit reluctant to disclose the following, but that the heck ...
Perhaps the most effective felt cleaner is soap and water. It's considerably easier and more pleasant to work with than naphtha, etc., it's much, much less expensive, and it does a better job than those flammable compounds at getting out those really nasty, greasy sweat stains that form at the bandline on well-used hats. Such has been my experience, anyway. Soak and scrub. Soak and scrub. Rinse, rinse, rinse. We very rarely see examples of such hats posted here, by the way, but "work" hats (Westerns, usually), the kind that get worn for years on end in hot and cold weather by people who routinely work up a sweat, can be so dirty at the bandline that you can't even see the felt through all the funk. It's impregnated clear through with a combination of sweat and dirt. The surface is often shiny with it. But it can indeed be cleaned almost good as new. But you gotta take the hat apart and put it back together again. And you need to reblock it. And flange it. No shortcuts. So it's considerably more work that just soaking a hat whole in a bucket of camp fuel.
FWIW (keeping in mind that I'm no chemist), I've used both VM&P (varnish maker's and painter's) naphtha (from the paint department at hardware store) and Coleman brand camp fuel. They sure don't look or smell like they're the same thing.
Donning a pair of rubber gloves and scrubbing the naphtha (or whatever solvent you're using) into the felt might get out some soiling that the soaking alone will leave in. But if you're not taking the hat apart, well, getting at some of that soiling might be difficult, if not impossible.
I'm a bit reluctant to disclose the following, but that the heck ...
Perhaps the most effective felt cleaner is soap and water. It's considerably easier and more pleasant to work with than naphtha, etc., it's much, much less expensive, and it does a better job than those flammable compounds at getting out those really nasty, greasy sweat stains that form at the bandline on well-used hats. Such has been my experience, anyway. Soak and scrub. Soak and scrub. Rinse, rinse, rinse. We very rarely see examples of such hats posted here, by the way, but "work" hats (Westerns, usually), the kind that get worn for years on end in hot and cold weather by people who routinely work up a sweat, can be so dirty at the bandline that you can't even see the felt through all the funk. It's impregnated clear through with a combination of sweat and dirt. The surface is often shiny with it. But it can indeed be cleaned almost good as new. But you gotta take the hat apart and put it back together again. And you need to reblock it. And flange it. No shortcuts. So it's considerably more work that just soaking a hat whole in a bucket of camp fuel.