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Might be slightly off-topic, and not quite homemade, but have you tried the commercial 'crystal' deodorants? 100% natural, completely odorless. They're not antiperspirants, but trust me, I have been using mine for over a year and I've never found myself sweating excessively, or smelling. Personally I'd much rather my skin be able to breathe and sweat a bit rather than clogging up my underarms.
I've had issues with these staining my clothes. I think it may be the alum in them. They seem to stain whites almost as bad as commerical deodorants, but it could be my body chemistry.